Independent Publications | Postdoctoral, Graduate and Undergraduate Publications | Invited Lectures



(49) Evans, P. J.; Zakharov, L. N.; Jasti, R. "Synthesis of Carbon Nanohoops Containing Thermally cis Azobenzene." Manuscript submitted
(48) Qiu, L.; Peña-Alvarez, M.; Taravillo, M.; Evans, P. J.; Darzi, E. R.; Jasti, R.; Burrezo, P. M.; López Navarrete, J. T; Baonza, V. G.; Casado, J.; Kertesz, M. "High Pressure Chemistry and the Mechanochemical Polymerization of [5]-Cyclo-p-phenylene." Manuscript submitted
(47) Van Raden, J. M.; Leonhardt, E. J.; Zakharov, L. N.; Lonergan, M. C.; Jasti, R. "Assembling Nanohoops Into Non-Covalent Nanotubes via Organofluorine Interactions." Manuscript submitted
(46) Li, P.; Zakharov, L. N.; Jasti, R. "A Molecular Propeller with Three Nanohoop Blades: Synthesis, Characterization, and Solid State Packing." Angew. Chem. Int. Ed. 2017, Accepted manuscript
(45) Van Raden, J. M.; Louie, S.; Zakharov, L. N.; Jasti, R. "2,2'-Bipyridyl-embedded Cycloparaphenylenes as a General Strategy to Investigate Nanohoop-based Coordination Complexes." J. Am. Chem. Soc. 2017, 139, 2936-2939.
(44) Darzi, E. R.; White, B. W.; Loventhal, L. K.; Zakharov, L. N.; Jasti, R. "An Operationally Simple and Mild Oxidative Homocoupling of Aryl Boronic Esters to Access Conformationally Constrained Macrocycles." J. Am. Chem. Soc. 2017, 139, 3106-3114.
(43) Taber, B.; Gervasi, C.; Mills, J.; Kislitsyn, D.; Darzi, E. D.; Crowley, W.; Jasti, R.; Nazin, G. "Quantum Confinement of Surface Electrons by Molecular Nanohoop Corrals." J. Phys. Chem. Lett. 2016, 7, 3073-3077.
(42) Golder, M. R.; Colwell, C. E.; Wong, B. M.; Zakharov, L. N.; Zhen, J.; Jasti, R. "Iterative Reductive Aromatization/Ring-Closing Metathesis Strategy Towards the Synthesis of Strained Aromatic Belts."J. Am. Chem. Soc. 2016, 138, 6577-6582.
(41) Peña Alvarez, Miriam; Ruiz Delgado, M. Carmen; Taravillo, Mercedes; Baonza, Valentín; López Navarrete, Juan T.; Evans, Paul; Jasti, Ramesh; Yamago, Shigeru; Kertesz, Miklos; Casado, Juan. "The Raman Fingerprint of Cyclic Conjugation: The case of the Stabilization of Cations and Dications in Cycloparaphenylenes." Chem. Sci. 2016, 7, 3494-3499.
(40) Jackson, E. P.; Sisto, T. J.; Darzi, E. D.; Jasti, R. "Probing Diels-Alder Reactivity on a Model CNT Sidewall." Tetrahedron. 2016, 72, 3754-3758.
Invited article for Garg Tetrahedron Young Investigator Award Symposium in Print issue.

(39) Li, P.; Wong, B. M.; Zakharov, L. N.; Jasti, R. "Investigating the Reactivity of 1,4-Anthracene-Incorporated Cycloparaphenylene."Org. Lett.2016, 18, 1574-1577.
Abstract Image
(38) Sisto, T. J.; Zakharov, L. N.; White, B. M.; Jasti, R. "Towards Pi-Extended Cycloparaphenylenes as Seeds for CNT Growth: Investigating Strain Relieving Ring-Openings and Rearrangements." Chem. Sci., 2016, 7, 3681-3688.

Graphical abstract: Towards pi-extended cycloparaphenylenes as seeds for CNT growth: investigating strain relieving ring-openings and rearrangements

(37) Van Raden, J. M.; Darzi, E. R.; Zakharov, L. N.; Jasti, R. "Synthesis and Characterization of a Highly Strained Donor- Acceptor Nanohoop." Org. Biomol. Chem., 2016,14, 5721-5727.
Invited Article for the New Talent themed collection
Selected for 2016 Hot Articles in Organic and Biomolecular Chemistry themed collection.

(36) Alvarez, M. P.; Qiu, L.; Delgado, M. C. R.; Taravillo, M.; Baonza, V. G.; Yamago, S.; Jasti, R.; Navarrete, J. T. L.; Casado, J.; Kertesz, M. "From Linear to Cyclic Oligoparaphenylenes: Electronic and Molecular Changes Traced in the Vibrational Raman Spectra and Reformulation of the Bond Length Alternation Pattern."Phys. Chem. Chem. Phys., 2016, 18, 11683-11692.

(35) Talipov, M.; Jasti, R.; Rathore, R. "A Circle Has No End: Role of Cyclic Topology and Accompanying Structural Reoganization on the hole Distribution in Cyclic and Linear Poly-p-phenylene Molecular Wires." J. Am. Chem. Soc. 2015, 137, 14999.
(34) Darzi, E. R.; Hirst, E. S.; Weber, C. D.; Zakharov, L. N.; Lonergan, M. C.; Jasti, R. "Synthesis, Properties, and Design Principles of Donor-Acceptor Nanohoops." ACS Cent. Sci. 2015, 1, 335-342.
Featured in ACS Cent. Sci.: First Reaction (October 2015)
Highlited in Around the UO
(33) Hines, D.; Darzi, E. R.; Jasti, R.; Kamat, P. "Carbon Nanohoops: Excited Singlet and Triplet Behavior of aza[8]CPP and 1,15-diaza[8]CPP." J. Phys. Chem. A 2015, 119, 8083.

(32) Kayahara, E.; Patel, V. K.; Xia, J.; Jasti, R.; Yamago, S. "Selective and Gram-scale Synthesis of [6]Cycloparaphenylene." Synlett 2015, 26, 1615.

(31) Darzi, E. R.; Jasti, R. "The Dynamic Size-Dependent Properties of [5]-[12] Cycloparaphenylenes." Chem. Soc. Rev. 2015, 44, 6401. Invited Publication in "Challenges in Aromaticity: 150 Years after Kekule's Benzene" Themed Issue.

(30) Golder, M. R.; Jasti, R. "Synthesis of the Smallest Carbon Nanohoops and the Emergence of Unique Physical Phenomena." Acc. Chem. Res. 2015, 48, 557.

(29) Chen, H.; Golder, M. R.; Wang, F.; Doorn, S. K.; Jasti, R.; Tretiak, S.; Swan, A. K."Raman-Active Modes of Even-Numbered Cycloparaphenylenes: Comparisons between Experiments and Density Functional Theory (DFT) Calculations with Group Theory Arguments." J. Phys. Chem. C 2015, 119, 2879.

(28) Adamska, L.; Nayyar, I.; Chen, H.; Swan, A. K.; Oldani, N.; Fernandez-Alberti, S.; Golder, M. R.; Jasti, R, Doorn, S. K.; Tretiak, S. "Self-trapping of excitons, violation of Condon approximation and efficient fluorescence in conjugated cycloparaphenylenes." Nano Lett. 2014, 14, 6539.

(27) Reddy, V. S.; Camacho, C.; Xia, J.; Jasti, R.; Irle, S. "Quantum Dynamics Simulations Reveal Vibronic Effects on the Optical Properties of [n]Cycloparaphenylenes." J. Chem. Theory Comput. 2014, 10, 4025.

(26) Alvarez, M. P.; Burrezo, P. M.; Kertesz, M.; Yamago, S.; Xia, J.; Jasti, R.; López Navarrete, J. T.; Taravillo, M.; Baonza, V. G.; Casado, J. "Properties of Sizeable [n]Cycloparaphenylenes as Ultrashort Single-Wall Carbon Nanotubes by Raman Spectroscopy: Structural and Electron-Transfer Responses Under Pressure Stress." Angew. Chem. Int. Ed. 2014, 53, 7033.

(25) Evans, P. J.*; Darzi, E. R.*; Jasti, R. "Efficient Room-Temperature Synthesis of a Highly Strained Carbon Nanohoop Fragment of Buckminsterfullerene." Nat. Chem. 2014, 6, 404.
Highlighted on Prof. Andrei Yudin's amphoteros blog
Featured in Nature Chemistry News & Views (April 2014)

(24) Hines, D.; Darzi, E. R.; Jasti, R.; Kamat, P. "Carbon Nanohoops: Excited Singlet and Triplet Behavior of [9]- and [12]-cycloparaphenylene." J. Phys. Chem. A. 2014, 118, 1595.

(23) Li, P.; Sisto, T. J.; Darzi, E. R.; Jasti, R. "The Effects of Cyclic Conjugation and Bending on the Optoelectronic Properties of Oligophenylenes." Org. Lett. 2014, 16, 182.

(22) Chen, H.; Golder, M. R.; Wang, F.; Jasti, R.; Swan, A. K. "Raman Spectroscopy of Carbon Nanohoops." Carbon 2014, 67, 203.

(21) Golder, M. R.; Wong, B. M.; Jasti, R. "Photophysical and Theoretical Investigations of the [8]Cycloparaphenylene Radical Cation and its Charge-Resonance Dimer." Chem. Sci. 2013, 4, 4285.
Highlighted in the Chemical Science "Physical Chemistry Themed Collection"
Featured in RSC Blogs

(20) Evans, P. J.; Jasti, R. "Molecular Belts." Top. Curr. Chem. 2013.

(19) Zabula, A. V.; Filatov, A. S.; Xia, J.; Jasti, R.; Petrukhina, M. A. "Tightening the Nanobelt Upon Multi-Electron Reduction." Angew. Chem. Int. Ed. 2013, 55, 5033.

(18) Hirst, E, S.; Jasti, R. "Bending Benzene: Syntheses of [n]Cycloparaphenylenes." J. Org. Chem. 2012, 77, 10473.
Invited Synopsis article.

(17) Xia, J.; Golder, M. R.; Foster, M, E.; Wong, B. M.; Jasti, R. "Synthesis, Characterization, and Computational Studies of Cycloparaphenylene Dimers." J. Am. Chem Soc. 2012,134, 19709.
Highlighted in Steven Bachrach's Computational Organic Chemistry

(16) Darzi, E. R.; Sisto, T. J.; Jasti, R. "Selective Syntheses of [7]- [12]Cycloparaphenylenes Using Orthogonal Suzuki-Miyaura Coupling Rections." J. Org. Chem. 2012, 77, 6624.

(15) Xia, J.; Bacon, J. W.; Jasti, R. "Gram-Scale Synthesis and Crystal Structures of [8]- and [10]CPP, and the Solid-State Structure of C60@[10]CPP." Chem. Sci. 2012, 3, 3018.
Highlighted in C&E News (July 18, 2012): "Nanohoops Scaled up 100-fold"
Highlighted in Synfacts: "Cycloparaphenylenes by the Gram"
Top ten most accessed articles in July 2012

(14) Sisto, T. J.; Tian, X.; Jasti, R. "Synthesis of Tetraphenyl-Substituted [12]Cycloparaphenylene: Towards a Rationally Designed Ultra-Short Carbon Nanotube." J. Org. Chem. 2012, 77, 5857.

(13) Sisto, T. J.; Jasti, R. "Overcoming Molecular Strain: Synthesis of [7]Cycloparaphenylene." Synlett 2012, 23, 483.
Synpacts featured article

(12) Xia, J.; Jasti, R. "Synthesis, Characterization, and Crystal Structure of [6]Cycloparaphenylene." Angew. Chem. Int. Ed. 2012, 51, 2474.
Highlighted in Synfacts: "Synthesis of the Smallest Nanohoop"

(11) Tian, X.; Jasti, R.  “Syntheses of Cycloparaphenylenes:  The Shortest-Possible Segments of Armchair Carbon Nanotubes.”  In Fragments of Fullerenes and Carbon Nanotubes:  Designed Synthesis, Unusual Reactions, and Coordination Chemistry; Petrukhina, M.A., Scott, L. T. Ed.; Wiley, 2011.

(10) Hirst, E. S.; Wang, F.; Jasti, R. "Theoretical Analysis of [5.7]nCyclacenes: Closed-Shell Cyclacene Isomers." Org. Lett. 2011, 13, 6220.

(9) Sisto, T. J.; Golder, M. R.; Hirst, E. S.; Jasti, R. "Selective Synthesis of Strained [7]Cycloparaphenylene: An Orange-Emitting Fluorophore." J. Am. Chem. Soc. 2011, 133, 15800.
Highlighted in Synfacts: "The Smaller the Redder"

(8) Jasti, R.; Bertozzi, C. R.  “Progress and Challenges for the Bottom-Up Synthesis of Carbon Nanotubes with Discrete Chirality.”  Chem. Phys. Lett. 2010, 494, 1-7.
Featured on the cover of the journal.
Invited Frontier Article.



(7) Jasti, R.; Bhattacharjee, J.; Neaton, J. B.; Bertozzi, C. R. "The Synthesis, Characterization, and Theory of [9]-, [12]-, and [18]Cycloparaphenylene: Carbon Nanohoop Structures." J. Am. Chem. Soc. 2008, 130, 17646-17647.
Featured in C & E News: "Nanotube Building Block Created".

(6) Van Orden, L. J.; Jasti, R.; Rychnovsky, S. D.  “Product Class 1:  Dialkyl Ethers. Synthesis  from Esters, Aldehydes, Ketones, and Acetals by Reduction or Alkylation.”  In Science of Synthesis; Forsyth, C, J., Jacobsen, E. N. Ed.; Georg Thieme Verlag KG: Stuttgart, 2008; Vol. 37, pp. 9-46.

(5) Jasti, R.; Rychnovsky, S. D.  “Racemization in Prins Cyclization Reactions.”  J. Am. Chem. Soc. 2006, 128, 13640-13648.

(4) Jasti, R.; Rychnovsky, S. D.  “Solvolysis of a Tetrahydropyranyl Mesylate: Mechanistic Implications for the Prins Cyclization, 2-Oxonia-Cope Rearrangement, and Grob Fragmentation.”  Org. Lett. 2006, 8, 2175-2178.

(3) Jasti, R.; Anderson, C. D; Rychnovsky, S. D. “Utilization of an Oxonia-Cope Rearrangement as a Mechanistic Probe for Prins Cyclizations.”  J. Am. Chem. Soc. 2005, 127, 9939-9945.

(2) Jasti, R.; Vitale, J.; Rychnovsky, S. D. “Axial-Selective Prins Cyclizations by Solvolysis of α-Bromo Ethers.” J. Am. Chem. Soc. 2004, 126, 9904-9905.

(1) Hicks, J. F.; Templeton, A. C.; Chen, S.; Sheran, K. M.; Jasti, R.; Murray, R. W.; Debord, J.;  Schaaff, T. G.; Whetten, R. L. “The Monolayer Thickness Dependence of Quantized Double-Layer Capacitances of Monolayer-Protected Gold Clusters.” Anal. Chem. 1999, 71, 3703-3711. 



(55) 100th Canandian Society for Chemistry Conference, Toronto (May 28, 2017)
(54) University of Southern California, Symposium in Honor of Carolyn Bertozzi (March 31, 2017)
(53) University of Houston (March 21, 2017)
(52) California Polytechnic State University (February 24, 2017)
(51) Flow Chemistry Congress 2016 (November 3, 2016)
(50) University of California, Riverside (June 1, 2016)
(49) Eastern Washington University (April 14, 2016)
(48) Oregon State University (January 28, 2016)
(47) Pacifichem 2015, Hawaii (December 15, 2015)
(46) 3rd Erlangen Symposium on Synthetic Carbon Allotropes, Erlangen, Germany (October 4, 2015)
(45) Idaho State University (September 25, 2015)
(44) 16th International Symposium on Novel Aromatic Compounds (ISNA-16), Madrid, Spain (July 5, 2015)
(43) Université de Montréal (April 22, 2015)
(42) University of California, Santa Barbara (March 13, 2015)
(41) Georgetown University (February 26, 2015)
(40) Auburn University (December 4, 2014)
(39) Colorado State University (November 3, 2014)
(38) Curved Organic pi-Molecules and Materials (CURO-pi), Kyoto, Japan (October 20, 2014)
(36) Fusion Conference: "From Carbon-Rich Molecules to Carbon-Based Materials", El Jadida, Morocco (September 22, 2014)
(35) SOCCER Graduate Symposium, Memorial University of Newfoundland (August 14, 2014)
(34) University of California, Berkeley (April 25, 2014)
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(32) University of Minnesota (April 10, 2014)
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(18) California Institute of Technology (November 13, 2013)
(17) Northeastern Section of the American Chemical Society Meeting, Boston, MA (October 10, 2013)
(16) University of New Hampshire (September 24, 2013)
(15) University of Massachusetts, Lowell (September 13, 2013)
(14) Young Academic Investigators Symposium, Fall 2013 ACS, Indianapolis, IN (September 8, 2013)
(13) 2nd International RSC Crystal & Graphene Symposium-2013, Waltham, MA (September 4, 2013)
(12) PerkinElmer, Boston, MA (April 23, 2013)
(11) Columbia University (April 3, 2013)
(10) University of Oregon (February 18, 2013)
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(8) University of California, Irvine (February 13, 2013)
(7) University of Vermont (January 24, 2013)
(6) University at Albany-SUNY (October 2, 2012)
(5) Agilent Technologies, Inc. Cupertino, CA (July 16, 2012)
(4) Gordon Research Conference: "Graphitic Carbon Materials, Chemistry and Physics of,". Davidson College (June 20, 2012)
(3) University of Massachusetts, Dartmouth (February 22, 2012)
(2) 14th International Symposium on Novel Aromatics, Eugene, Oregon (July 27, 2011)
(1) Boston College (January 26, 2010)